A neutral diphosphene radical: synthesis, electronic structure and white phosphorus activation-Reference-Cited by-同舟云学术

A neutral diphosphene radical: synthesis, electronic structure and white phosphorus activation

Published:2024 Issue:65 Volume:60 Page:8537-8540
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Haberstroh Jan¹^ORCID,Taube Clemens¹,Fidelius Jannis¹^ORCID,Schulz Stephen¹^ORCID,Israel Noel²^ORCID,Dmitrieva Evgenia²^ORCID,Gomila Rosa M.³^ORCID,Frontera Antonio³^ORCID,Wolf Robert⁴^ORCID,Schwedtmann Kai¹^ORCID,Weigand Jan J.¹⁵^ORCID

Affiliation:

1. Chair of Inorganic Molecular Chemistry, Faculty of Chemistry and Food Chemistry, Technische Universität Dresden, 01069 Dresden, Germany

2. Leibnitz Institute for Solid State and Materials Research Dresden, 01069 Dresden, Germany

3. Department of Chemistry, Universitat de les Illes Balears, 07122 Palma de Mallorca, Spain

4. Institute of Inorganic Chemistry, Universität Regensburg, 93040 Regensburg, Germany

5. Department of Chemistry and Polymer Science, Stellenbosch University, Stellenbosch, South Africa

Abstract

The mixed-substituted diphosphene radical has been isolated and characterised. Upon reaction with white phosphorus, the compound forms an octaphosphane.

Funder

Technische Universität Dresden

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC02200A

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