Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism-Reference-Cited by-同舟云学术

Unsymmetrical 1,1-diborated multisubstituted sp3-carbons formed via a metal-free concerted-asynchronous mechanism

Published:2015 Issue:37 Volume:13 Page:9659-9664
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Cuenca Ana B.¹²³⁴,Cid Jessica¹²³⁴,García-López Diego¹²³⁴,Carbó Jorge J.¹²³⁴,Fernández Elena¹²³⁴

Affiliation:

1. Department Química Física i Inorgànica

2. University Rovira i Virgili

3. Tarragona

4. Spain

Abstract

We have experimentally proved and computationally rationalized the unsymmetrical 1,1-diboration of diazo compounds, formed in situ from aldehydes and cyclic and non-cyclic ketones, in the absence of any transition metal complex.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01523E

Reference33 articles.

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2. Chemoselective Suzuki Coupling of Diborylmethane for Facile Synthesis of Benzylboronates

3. Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

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