The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn

The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn–Teller effect

Published:2022 Issue:2 Volume:13 Page:510-521
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sigmund Lukas M.¹^ORCID,Maier Rouven¹,Greb Lutz¹²^ORCID

Affiliation:

1. Anorganisch-Chemisches Institut, Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, 69120 Heidelberg, Germany

2. Department of Chemistry and Biochemistry – Inorganic Chemistry, Freie Universität Berlin, Fabeckstr. 34/36, 14195 Berlin, Germany

Abstract

The tetrahedron is the primary structural motif among the p-block elements and determines the architecture of our bio- and geosphere. This study sheds light on its stereochemical inversion process.

Funder

Studienstiftung des Deutschen Volkes

Horizon 2020

Deutsche Forschungsgemeinschaft

Baden-Württemberg Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D1SC05395G

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