A short total synthesis of (±)-mersicarpine <i>via</i> visible light-induced cascade photooxygenation-Reference-Cited by-同舟云学术

A short total synthesis of (±)-mersicarpine via visible light-induced cascade photooxygenation

Published:2022 Issue:36 Volume:58 Page:5467-5469
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Frahm Mario¹,Voss Alice¹,Brasholz Malte¹²^ORCID

Affiliation:

1. Institute of Chemistry, University of Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany

2. Leibniz-Institut für Katalyse e.V., Albert-Einstein-Str. 29a, 18059 Rostock, Germany

Abstract

A short synthesis of the Kopsia alkaloid (±)-mersicarpine is enabled by the visible light-driven photooxygenation of a tetrahydrocarbazole, generating a perhydropyrido[1,2-a]indole dione as the immediate precursor to the natural product.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC01316A

Reference23 articles.

1. Mersicarpine, an unusual tetracyclic dihydroindole alkaloid incorporating a seven-membered imine ring

2. Total Synthesis of (±)-Mersicarpine

3. Total Synthesis of (−)-Mersicarpine

4. Concise Total Synthesis of (−)-Mersicarpine

5. Enantiocontrolled Total Synthesis of (−)-Mersicarpine

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