Manganese protoporphyrin IX reconstituted myoglobin capable of epoxidation of the CC bond with Oxone®-Reference-Cited by-同舟云学术

Manganese protoporphyrin IX reconstituted myoglobin capable of epoxidation of the CC bond with Oxone®

Published:2016 Issue:10 Volume:3 Page:1236-1244
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Cai Yuan-Bo¹²³⁴⁵,Yao Si-Yu¹²³⁴⁵,Hu Mo⁶³⁴⁵⁷,Liu Xiaoyun⁶³⁴⁵⁷,Zhang Jun-Long¹²³⁴⁵

Affiliation:

1. Beijing National Laboratory for Molecular Sciences

2. State Key Laboratory of Rare Earth Materials Chemistry and Applications

3. College of Chemistry and Molecular Engineering

4. Peking University

5. Beijing 100871

6. Institute of Analytical Chemistry and Synthetic and Functional Biomolecules Center

7. P. R. China

Abstract

Myoglobin with three distal histidines stabilizes KHSO₅, facilitates the O–O bond heterocleavage, and firstly catalyzes epoxidation with the MnPPIX cofactor.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/QI/C6QI00120C

Reference65 articles.

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