A mild and facile synthesis of aryl and alkenyl sulfides via copper-catalyzed deborylthiolation of organoborons with thiosulfonates

Author:

Yoshida Suguru12345,Sugimura Yasuyuki67385,Hazama Yuki12345,Nishiyama Yoshitake12345,Yano Takahisa12345,Shimizu Shigeomi67385,Hosoya Takamitsu12345

Affiliation:

1. Laboratory of Chemical Bioscience

2. Institute of Biomaterials and Bioengineering

3. Tokyo Medical and Dental University

4. Tokyo 101-0062

5. Japan

6. Department of Pathological Cell Biology

7. Medical Research Institute

8. Tokyo 113-8510

Abstract

A simple, efficient, and odorless deborylthiolation of aryl- and alkenylborons with thiosulfonates has been achieved under mild conditions using a copper catalyst.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference82 articles.

1. P. Metzner , A.Thuillier, A. R.Katritzky, O.Meth-Cohn and C. S.Rees, Sulfur Reagents in Organic Synthesis, Academic Press, London, 1994

2. G. H. Whitham , Organosulfur Chemistry, Oxford University Press, Northamptonshire, 1995

3. R. J. Cremlyn , An Introduction to Organosulfur Chemistry, Wiley-VCH, Weinheim, 1996

4. T. Takata , T.Murai, S.Ogawa and S.Sato, Contemporary Organosulfur Chemistry: Fundamentals and Applications, Kagaku-Dojin Publishing, Tokyo, 2014

5. Biosynthesis of some sulfur-containing natural products investigations of the mechanism of carbon-sulfur bond formation

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