One-pot production of diethyl maleate via catalytic conversion of raw lignocellulosic biomass

Author:

Cai Zhenping12ORCID,Chen Rujia1,Zhang Hao3,Li Fukun1,Long Jinxing1ORCID,Jiang Lilong2ORCID,Li Xuehui1ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Pulp & Paper Engineering State Key Laboratory of China, South China University of Technology, Guangzhou 510640, China

2. National Engineering Research Center of Chemical Fertilizer Catalysts (NERC-CFC), Fuzhou University, Fuzhou 350002, China

3. Institute of Functional Nano and Soft Materials Laboratory (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices, Soochow University, Suzhou 215123, China

Abstract

Selective conversion of raw biomass to diethyl maleate was conducted by polyoxometalate ionic liquid [BSmim]CuPW12O40, where up to 329.6 mg g−1 DEM yield, 70.3 % selectivity, and 20.8% carbon yield were obtained at 170 °C for 4 h and 1 MPa O2.

Funder

Natural Science Foundation of Guangdong Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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