“Broken-hearted” carbon bowl via electron shuttle reaction: energetics and electron coupling-Reference-Cited by-同舟云学术

“Broken-hearted” carbon bowl via electron shuttle reaction: energetics and electron coupling

Published:2021 Issue:19 Volume:12 Page:6600-6606
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Leith Gabrielle A.¹²³⁴^ORCID,Rice Allison M.¹²³⁴,Yarbrough Brandon J.¹²³⁴,Kittikhunnatham Preecha¹²³⁴,Mathur Abhijai¹²³⁴,Morris Nicholas A.¹²³⁴,Francis Megan J.¹²³⁴,Berseneva Anna A.¹²³⁴,Dhull Poonam¹²³⁴^ORCID,Adams Richard D.¹²³⁴^ORCID,Bobo M. Victoria¹²³⁴,Vannucci Aaron A.¹²³⁴^ORCID,Smith Mark D.¹²³⁴,Garashchuk Sophya¹²³⁴,Shustova Natalia B.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. University of South Carolina

3. Columbia

4. USA

Abstract

An electron shuttle contributed to breaking corannulene's heart through a unique one-step reductive CC bond cleavage in the traditionally robust π-bowl. The heartbreak did not stop there as “broken analogs” were developed through a solution-phase route.

Funder

Camille and Henry Dreyfus Foundation

Office of Experimental Program to Stimulate Competitive Research

National Science Foundation

Alfred P. Sloan Foundation

Research Corporation for Science Advancement

Institute for Advanced Study

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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