Ionic liquids of superior thermal stability. Validation of PPh4+ as an organic cation of impressive thermodynamic durability
Author:
Affiliation:
1. Department of Chemistry
2. University of South Alabama
3. Mobile
4. USA
Abstract
When appended to the tetraphenylphosphonium cation, organic groups containing aliphatic C–H bonds are burned away at high temperatures in the presence of O2. However, the parent cation remains unscathed, demonstrating its remarkable thermal stability.
Funder
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/RA/D0RA03220D
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Cited by 4 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Correction: Ionic liquids of superior thermal stability. Validation of PPh4+ as an organic cation of impressive thermodynamic durability;RSC Advances;2023
2. Thermal decomposition and volatility of ionic liquids: Factors, evaluation and strategies;Journal of Molecular Liquids;2022-11
3. Linking the Thermal and Electronic Properties of Functional Dicationic Salts with Their Molecular Structures;ACS Sustainable Chemistry & Engineering;2021-04-27
4. Understanding liquid–liquid equilibria in binary mixtures of hydrocarbons with a thermally robust perarylphosphonium-based ionic liquid;RSC Advances;2021
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