Electron transfer-induced reduction of organic halides with amines

Author:

Fukuyama Takahide12345ORCID,Fujita Yuki12345,Miyoshi Hayato12345,Ryu Ilhyong12345ORCID,Kao Shih-Chieh6789,Wu Yen-Ku6789ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Osaka Prefecture University

4. Osaka 599-8531

5. Japan

6. Department of Applied Chemistry

7. National Chiao Tung University

8. Hsinchu

9. Taiwan

Abstract

UV light-induced reduction of vinyl and aryl halides with triethylamine proceeded smoothly to give the corresponding reduced products. High temperature heating also caused the reduction and DABCO also served as a good reducing reagent.

Funder

Japan Society for the Promotion of Science

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference47 articles.

1. V. E. Ziffle and S. P.Fletcher , Reduction of Saturated Alkyl Halides to Alkanes , in Comprehensive Organic Synthesis , ed. G. A. Molander and P. Knochel , Elsevier , Oxford , 2nd edn, 2014 , vol. 8, pp. 999–1010

2. J. D. Nguyen , E. M.D’Amato and C. R. J.Stephenson , Reduction of Alkenyl Halides to Alkenes, and of Aryl Halides and Related Compounds to Arenes , in Comprehensive Organic Synthesis , ed. G. A. Molander and P. Knochel , Elsevier , Oxford , 2nd edn, 2014 , vol. 8, pp. 1123–1142

3. Reduction of Organic Compounds by Organotin Hydrides

4. Rate constants and Arrhenius parameters for the reactions of primary, secondary, and tertiary alkyl radicals with tri-n-butyltin hydride

5. Tin Hydride Substitutes in Reductive Radical Chain Reactions

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