Direct measurements of the total rate constant of the reaction NCN + H and implications for the product branching ratio and the enthalpy of formation of NCN-Reference-Cited by-同舟云学术

Direct measurements of the total rate constant of the reaction NCN + H and implications for the product branching ratio and the enthalpy of formation of NCN

Published:2014 Issue:23 Volume:16 Page:11647-11657
ISSN:1463-9076
Container-title:Phys. Chem. Chem. Phys.
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Faßheber Nancy¹²³,Dammeier Johannes¹²³,Friedrichs Gernot¹²³

Affiliation:

1. Institut für Physikalische Chemie

2. Christian-Albrechts-Universität zu Kiel

3. 24118 Kiel, Germany

Abstract

The high-temperature rate constant of the reaction NCN + H, a key reaction for modelling NO_x formation in flames, has been directly measured for the first time.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CP/C4CP01107D

Reference47 articles.

1. Formation of nitric oxide in premixed hydrocarbon flames

2. The spin-conserved reaction CH+N2→H+NCN: A major pathway to prompt no studied by quantum/statistical theory calculations and kinetic modeling of rate constant

3. Kinetics of CH + N2 Revisited with Multireference Methods

4. Ab Initio Chemical Kinetics for H + NCN: Prediction of NCN Heat of Formation and Reaction Product Branching via Doublet and Quartet Surfaces

5. Evidence of NCN as a flame intermediate for prompt NO

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