Gram-scale synthesis of porphycenes through acid-catalyzed oxidative macrocyclizations of E/Z-mixed 5,6-diaryldipyrroethenes-Reference-Cited by-同舟云学术

Gram-scale synthesis of porphycenes through acid-catalyzed oxidative macrocyclizations of E/Z-mixed 5,6-diaryldipyrroethenes

Published:2018 Issue:69 Volume:8 Page:39269-39273
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Ono Toshikazu¹²³⁴⁵^ORCID,Xu Ning¹²³⁴⁵,Koga Daiki¹²³⁴⁵,Ideo Toshihiro⁶⁷⁸⁹,Sugimoto Manabu⁶⁷⁸⁹^ORCID,Hisaeda Yoshio¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry

2. Graduate School of Engineering

3. Center for Molecular Systems (CMS)

4. Kyushu University

5. Fukuoka 819-0395

6. Faculty of Advanced Science and Technology

7. Kumamoto University

8. Kumamoto 860-8555

9. Japan

Abstract

A set of novel porphycenes was synthesized on a gram-scale in high overall yields by optimization of macrocyclization of E/Z-mixed 5,6-diaryldipyrroethenes.

Funder

Precursory Research for Embryonic Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA09040H

Reference40 articles.

1. Porphycene-a Novel Porphin Isomer

2. Porphycenes and Related Isomers: Synthetic Aspects

3. Porphycenes: Facts and Prospects in Photodynamic Therapy of Cancer

4. Blue Myoglobin Reconstituted with an Iron Porphycene Shows Extremely High Oxygen Affinity

5. C(sp3)–H Bond Hydroxylation Catalyzed by Myoglobin Reconstituted with Manganese Porphycene

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