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Probing the gas-phase structure of charge-tagged intermediates of a proline catalyzed aldol reaction – vibrational spectroscopy distinguishes oxazolidinone from enamine species

  • Published:2019 Issue:5 Volume:21 Page:2578-2586
  • ISSN:1463-9076
  • Container-title:Physical Chemistry Chemical Physics
  • language:en
  • Short-container-title:Phys. Chem. Chem. Phys.

Author:

Willms J. Alexander1234,Vidic Jandro56274,Barthelmes Janosch1234,Steinmetz Vincent89101112,Bredow Thomas56274,Maître Philippe89101112,Engeser Marianne1234ORCID

Affiliation:

1. Kekulé-Institute of Organic Chemistry and Biochemistry

2. University of Bonn

3. D-53121 Bonn

4. Germany

5. Mulliken Center for Theoretical Chemistry

6. Institute of Physical und Theoretical Chemistry

7. D-53115 Bonn

8. Laboratoire de Chimie Physique

9. Université Paris-Sud

10. CNRS, Université Paris-Saclay

11. Orsay

12. France

Abstract

Charge-tagging enables the detection of reaction intermediates which are probed by IRMPD spectroscopy in combination with theory.

Funder

Centre National de la Recherche Scientifique

Horizon 2020 Framework Programme

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference106 articles.

1. Asymmetric Organocatalysis , ed. A. Berkessel and H. Gröger , Wiley-VCH , Weinheim , 2005

2. Asymmetric Organocatalysis , ed. B. List , Springer , Berlin, Heidelberg , 2010

3. Im Goldenen Zeitalter der Organokatalyse

4. Introduction:  Organocatalysis

5. The advent and development of organocatalysis

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