Effective stabilization of a planar phosphorus(iii) center embedded in a porphyrin-based fused aromatic skeleton-Reference-Cited by-同舟云学术

Effective stabilization of a planar phosphorus(iii) center embedded in a porphyrin-based fused aromatic skeleton

Published:2017 Issue:12 Volume:8 Page:8231-8239
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Fujimoto Keisuke¹²³⁴⁵^ORCID,Osuka Atsuhiro¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Kyoto University

4. Kyoto

5. Japan

Abstract

Planar phosphorus(iii) centers were effectively stabilized by structural constraint as well as aromatic stabilization in porphyrin-based fused π-conjugated frameworks.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC03882H

Reference48 articles.

1. Effect of structure on the rate of pyramidal inversion of acyclic phosphines

2. Phosphorus lone pairs stabilization of carbocations: the synthesis and dynamics of unsymmetrical methylene phosphonium ions

3. Stable Versions of Transient Push-Pull Carbenes: Extending Lifetimes from Nanoseconds to Weeks

4. UPE studies of conjugation involving Group 5A elements. 1. Phenylphosphines

5. Interaction of frontier orbitals of Group 15 and Group 16 methides with the frontier orbitals of benzene

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