Controlling chemoselectivity in copper-catalyzed decarboxylative A3/A3 cross-couplings: direct formation of unsymmetrical 1,4-diamino-2-butynes
Author:
Affiliation:
1. College of Chemistry and Chemical Engineering
2. Shanghai University of Engineering Science
3. Shanghai
4. China
5. State Key Laboratory of Organometallic Chemistry
6. Shanghai Institute of Organic Chemistry
7. Chinese Academy of Sciences
Abstract
A direct cross-coupling of propiolic acid with two kinds of in situ formed iminiums has been achieved via a CuI/CuCl2-catalyzed decarboxylative A3/A3 domino process.
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/QO/C6QO00499G
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