DMAP-catalyzed esterification of pentaerythritol-derivatized POMs: a new route for the functionalization of polyoxometalates

Author:

Wu Pingfan12345,Xiao Zicheng5674,Zhang Jin5674,Hao Jian5674,Chen Jiake5674,Yin Panchao5674,Wei Yongge56748

Affiliation:

1. School of Chemical & Environmental Engineering

2. Hubei University of Technology

3. Wuhan 430068

4. China

5. Department of Chemistry

6. Tsinghua University

7. Beijing 100084

8. Key Laboratory of Cluster Science (Beijing Institute of Technology)

Abstract

A pentaerythritol-derived hexavanadate can be easily esterified with acid anhydrides using DMAP as a catalyst, providing a convenient way for the functionalization of polyoxometalates.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference49 articles.

1. M. T. Pope , in Comprehensive Coordination Chemistry II , ed. A. G. Wedd , Elsevier , Oxford , 2004 , p. 635

2. Polyoxometalate Chemistry: From Topology via Self-Assembly to Applications , ed. M. T. Pope and A. Müller , Kluwer , Dordrecht , 2001

3. C. L. Hill , in Comprehensive Coordination Chemistry II , ed. A. G. Wedd , Elsevier , Oxford , 2004 , p. 679

4. Polyoxometalate Chemistry for Nano-Composite Design , ed. T. Yamase and M. T. Pope , Kluwer Academic , New York , 2002

5. Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

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