Extended enantiopure ortho-phenylene ethylene (o-OPE)-based helical systems as scaffolds for supramolecular architectures: a study of chiroptical response and its connection to the CISS effect

Author:

Ortuño Ana M.1,Reiné Pablo1,Resa Sandra1,Álvarez de Cienfuegos Luis1ORCID,Blanco Victor1ORCID,Paredes José Manuel2,Mota Antonio J.3ORCID,Mazzeo Giuseppe45,Abbate Sergio45ORCID,Ugalde Jesus M.6,Mujica Vladimiro67,Longhi Giovanna45ORCID,Miguel Delia2ORCID,Cuerva Juan Manuel1ORCID

Affiliation:

1. Department of Organic Chemistry, Faculty of Science, Universidad de Granada (UGR), Unidad de Excelencia de Química (UEQ), E-18071 Granada, Spain

2. Department of Physical Chemistry, Faculty of Pharmacy, UGR-UEQ

3. Department of Inorganic Chemistry, Faculty of Science, UGR-UEQ

4. Department of Molecular and Translational Medicine, Università di Brescia, Brescia, Italy

5. Istituto Nazionale di Ottica – CNR, Brescia Research Unit, via Branze 45, 25123 Brescia, Italy

6. Kimika Fakultatea, Euskal Herriko Unibertsitatea and Donostia International Physics Center (DIPC), P. K. 1072, 20080 Donostia, Euskadi, Spain

7. Arizona State University, School of Molecular Sciences, Tempe, AZ 85287, USA

Abstract

Versatile enantiopure helical systems are described and are of interest owing to their intense chiroptical responses, their attractive architecture for metallosupramolecular chemistry and CISS effect.

Funder

Ministerio de Economía y Competitividad

Ministero dell’Istruzione, dell’Università e della Ricerca

Ikerbasque, Basque Foundation for Science

Ministerio de Ciencia e Innovación

Junta de Andalucía

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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