Measuring T1 relaxation in paramagnetic solids with solid-state NMR: a case study on the milling induced phase transition in Li6CoO4-Reference-Cited by-同舟云学术

Measuring T₁ relaxation in paramagnetic solids with solid-state NMR: a case study on the milling induced phase transition in Li₆CoO₄

Published:2023 Issue:17 Volume:25 Page:12065-12071
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guo Nianrui¹,Geng Fushan¹^ORCID,Lu Guozhong¹,Jiang Xinbiao¹,Li Chao¹^ORCID,Hu Bingwen¹^ORCID,Shen Ming¹^ORCID

Affiliation:

1. Shanghai Key Laboratory of Magnetic Resonance, State Key Laboratory of Precision Spectroscopy, School of Physics and Electronic Science, East China Normal University, Shanghai 200241, P. R. China

Abstract

A site-specific solid-state NMR T1 relaxation measurement method is developed to study the ball-milling induced phase transition in Li6CoO4.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

East China Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CP/D3CP00757J

Reference40 articles.

1. Materials’ Methods: NMR in Battery Research

2. Solid‐State NMR and MRI Spectroscopy for Li/Na Batteries: Materials, Interface, and In Situ Characterization

3. Superstructure control of first-cycle voltage hysteresis in oxygen-redox cathodes

4. Structurally stable Mg-doped P2-Na2/3Mn1−yMgyO2 sodium-ion battery cathodes with high rate performance: insights from electrochemical, NMR and diffraction studies

5. Evolution of Structure and Lithium Dynamics in LiNi0.8Mn0.1Co0.1O2 (NMC811) Cathodes during Electrochemical Cycling