Hydrogen evolution catalysis by molybdenum sulfides (MoSx): are thiomolybdate clusters like [Mo3S13]2− suitable active site models?

Author:

Grutza Marie-Luise12345,Rajagopal Ashwene6785,Streb Carsten6785ORCID,Kurz Philipp12345ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Freiburger Materialforschungszentrum (FMF)

3. Albert-Ludwigs-Universität Freiburg

4. 79104 Freiburg

5. Germany

6. Institut für Anorganische Chemie I

7. Universität Ulm

8. 89081 Ulm

Abstract

Recent results concerning molecular molybdenum sulfido clusters as model systems for heterogeneous hydrogen evolution catalysis by molybdenum sulfides are summarized and also compared to the related chemistry of the active site of the enzyme Mo-nitrogenase.

Funder

Deutsche Forschungsgemeinschaft

Klima- und Energiefonds

Universität Ulm

Ministerium für Wissenschaft, Forschung und Kunst Baden-Württemberg

Publisher

Royal Society of Chemistry (RSC)

Subject

Energy Engineering and Power Technology,Fuel Technology,Renewable Energy, Sustainability and the Environment

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