Silicon microfabricated reactor for operando XAS/DRIFTS studies of heterogeneous catalytic reactions

Author:

Venezia B.1234ORCID,Cao E.1234,Matam S. K.54678ORCID,Waldron C.1234,Cibin G.9104,Gibson E. K.5471112ORCID,Golunski S.678134ORCID,Wells P. P.5471415,Silverwood I.161718194ORCID,Catlow C. R. A.54678ORCID,Sankar G.202214,Gavriilidis A.1234ORCID

Affiliation:

1. Department of Chemical Engineering

2. University College London

3. London WC1E 7JE

4. UK

5. The UK Catalysis Hub

6. Cardiff Catalysis Institute

7. School of Chemistry

8. Cardiff University

9. Diamond Light Source Ltd.

10. Didcot OX11 0DE

11. The University of Glasgow

12. Glasgow G12 8QQ

13. Cardiff CF10 3AT

14. University of Southampton

15. Southampton SO17 1BJ

16. ISIS Pulsed Neutron and Muon Facility

17. Science and Technology Facilities Council

18. Rutherford Appleton Laboratory

19. Oxon

20. Department of Chemistry

21. London WC1H 0AJ

Abstract

A novel microreactor for operando XAS and DRIFTS studies of catalytic reactions is reported, exhibiting plug-flow, isothermal behaviour and absence of mass transfer resistances and dead volume, enabling time- and spatially-resolved experiments.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

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