Intermolecular C–H⋯O and n → π* and short intramolecular σ → π* interactions in the molybdenum(0) tetracarbonyl complex of a very twisted 14-membered tetraazaannulene macrocyclic ligand: structural and computational studies-Reference-Cited by-同舟云学术

Intermolecular C–H⋯O and n → π* and short intramolecular σ → π* interactions in the molybdenum(0) tetracarbonyl complex of a very twisted 14-membered tetraazaannulene macrocyclic ligand: structural and computational studies

Published:2019 Issue:35 Volume:21 Page:5222-5226
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Kia Reza¹²³⁴^ORCID,Hosseini Mahsa¹²³⁴,Abdolrahimi Amin¹²³⁴,Mahmoudi Melika¹²³⁴

Affiliation:

1. Chemistry Department

2. Sharif University of Technology

3. Tehran

4. Iran

Abstract

An interesting intermolecular n → π* interaction supported an intermolecular C–H⋯O interaction in a molybdenum tetracarbonyl complex of a substituted dibenzo-tetraazaannulene complex to consolidate the crystal packing in the solid state.

Funder

Sharif University of Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CE/C9CE01005J

Reference30 articles.

1. Aminomethylen-?-dicarbonylverbindungen als Komplexliganden. V. Neue konjugiert-unges�ttigte Neutralkomplexe mit vierzehngliedrigen, makrozyklischen Liganden

2. Recent developments in the chemistry of mono- and dinuclear complexes of the macrocyclic dianion, 5,7,12,14-tetramethyldibenzo[b,i][1,4,8,11] tetraazac

3. Dibenzotetraaza[14]annulenes: versatile ligands for transition and main group metal chemistry

4. Molybdenum and tungsten carbonyl complexes with a 14-membered macrocyclic ligand, dibenzo[b,i][1,4,8,11]tetra-azacyclotetradecine

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