Chiral octahedral complexes of Co(iii) as catalysts for asymmetric epoxidation of chalcones under phase transfer conditions

Author:

Larionov Vladimir A.123,Markelova Elina P.453,Smol'yakov Alexander F.123,Savel'yeva Tat'yana F.123,Maleev Victor I.123,Belokon Yuri N.123

Affiliation:

1. Nesmeyanov Institute of Organoelement Compounds

2. 119991 Moscow

3. Russia

4. D.Mendeleev University of Chemistry Technology of Russia

5. 125047 Moscow

Abstract

Stereochemically inert and positively charged chiral complexes of Co(iii) were shown to catalyze the asymmetric epoxidation of chalcones with H2O2 under phase transfer conditions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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