Aryl group transfer and C–P bond formation in the reaction of organonickel complexes with sodium 3,4,5-triphenyl-1,2-diphospholide

Author:

Sakhapov I. F.1,Zagidullin A. A.12ORCID,Gafurov Z. N.1,Khismatova D. K.13,Zaripov R. B.45ORCID,Kagilev A. A.13,Kantyukov A. O.13,Zueva E. M.16ORCID,Petrova M. M.6,Litvinov I. A.1ORCID,Miluykov V. A.1,Shmelev A. G.4,Sinyashin O. G.1,Yakhvarov D. G.13

Affiliation:

1. Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences, Arbuzov Street 8, Kazan, 420088, Russia

2. Institute of Fundamental Medicine and Biology, Kazan Federal University, Kremlyovskaya Street 18, Kazan, 420008, Russia

3. Alexander Butlerov Institute of Chemistry, Kazan Federal University, Kremlyovskaya Street 18, Kazan, 420008, Russia

4. Zavoisky Physical-Technical Institute, FRC Kazan Scientific Center, Russian Academy of Sciences, Sibirsky Tract 10/7, Kazan, 420029, Russia

5. Institute of Physics, Kazan Federal University, Kremlyovskaya Street 18, Kazan, 420008, Russia

6. Department of Inorganic Chemistry, Kazan National Research Technological University, Karl Marx Street 68, Kazan, 420015, Russia

Abstract

The reaction of [NiBr(aryl)(bpy)] organonickel complexes with sodium 1,2-diphospholide leads to unknown 1-aryl-1,2-diphospholes by aryl group transfer.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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