A new, double-inversion mechanism of the F− + CH3Cl SN2 reaction in aqueous solution
Author:
Affiliation:
1. College of Physics and Electronics
2. Shandong Normal University
3. Jinan
4. China
5. School of Science
6. Qilu University of Technology
Abstract
A new, double-inversion mechanism was discovered for the bimolecular nucleophilic substitution reaction F− + CH3Cl in aqueous solution.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP06195H
Reference53 articles.
1. Quantum dynamics of the Walden inversion reaction Cl−+CH3Cl→ClCH3+Cl−
2. Stepwise walden inversion in nucleophilic substitution at phosphorus
3. Ab Initio Direct Dynamics Trajectory Study of the Cl- + CH3Cl SN2 Reaction at High Reagent Translational Energy
4. Theoretical Analysis of Gas-Phase Front-Side Attack Identity SN2(C) and SN2(Si) Reactions with Retention of Configuration
5. Indirect Dynamics in a Highly Exoergic Substitution Reaction
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