Contrasting the group 6 metal–metal bonding in sodium dichromate(ii) and sodium dimolybdate(ii) polymethyl complexes: synthetic, X-ray crystallographic and theoretical studies
Author:
Affiliation:
1. WestCHEM
2. Department of Pure and Applied Chemistry
3. University of Strathclyde
4. Glasgow
5. UK
6. School of Chemistry
7. University of Glasgow
Abstract
Adding TMEDA to [M4Cr2Me8] (M = Li, Na) causes the Li complex to go mononuclear, whereas MeNa is extruded to give [Na3Cr2Me7] and a shortening of the Cr⋯Cr separation.
Funder
Royal Society
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C6DT04644D
Reference90 articles.
1. Stable Magnesium(I) Compounds with Mg-Mg Bonds
2. Decamethyldizincocene, a Stable Compound of Zn(I) with a Zn-Zn Bond
3. Synthesis of a Stable Compound with Fivefold Bonding Between Two Chromium(I) Centers
4. The Shortest Metal−Metal Bond Yet: Molecular and Electronic Structure of a Dinuclear Chromium Diazadiene Complex
5. Metal-Metal Distances at the Limit: A Coordination Compound with an Ultrashort Chromium-Chromium Bond
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