Modulation of the isomerization of iminothioindoxyl switches by supramolecular confinement

Author:

Doellerer Daniel1ORCID,Rückert Ann-Kathrin2ORCID,Doria Sandra34,Hilbers Michiel5,Simeth Nadja A.6ORCID,Buma Wybren Jan57ORCID,Di Donato Mariangela34ORCID,Feringa Ben L.1ORCID,Szymanski Wiktor18ORCID,Crespi Stefano2ORCID

Affiliation:

1. Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands

2. Department of Chemistry – Ångström Laboratory, Uppsala University, Box 523, 751 20 Uppsala, Sweden

3. ICCOM-CNR, via Madonna del Piano 10, 50019 Sesto Fiorentino, Italy

4. Laboratorio Europeo di Spettroscopia Non Lineare (LENS), via N. Carrara 1, 50019 Sesto Fiorentino, Italy

5. Van 't Hoff Institute for Molecular Sciences, University of Amsterdam, Science Park 904, 1098 XH, Amsterdam, The Netherlands

6. Institute for Organic and Biomolecular Chemistry, Department of Chemistry, University of Göttingen, Tammannstr. 2, 37077, Göttingen, Germany

7. Institute for Molecules and Materials, FELIX Laboratory, Radboud University, Toernooiveld 7c, 6525 ED, Nijmegen, The Netherlands

8. Medical Imaging Center, University Medical Center Groningen, University of Groningen, 9713 GZ Groningen, The Netherlands

Abstract

Confining iminothioindoxyl photoswitches within a supramolecular coordination cage imparts a bifurcation of the excited state isomerization pathway.

Funder

Vetenskapsrådet

H2020 Marie Skłodowska-Curie Actions

Ministerie van Onderwijs, Cultuur en Wetenschap

Publisher

Royal Society of Chemistry (RSC)

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