CuBr2-catalyzed diastereoselective allylation: total synthesis of decytospolides A and B and their C6-epimers-Reference-Cited by-同舟云学术

CuBr2-catalyzed diastereoselective allylation: total synthesis of decytospolides A and B and their C6-epimers

Published:2020 Issue:14 Volume:18 Page:2685-2695
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Padhi Birakishore¹²³⁴,Reddy G. Sudhakar¹²³⁴,Mallampudi N. Arjunreddy¹²³⁴,Choudhury Utkal Mani¹²³⁴,Mohapatra Debendra K.¹²³⁴^ORCID

Affiliation:

1. Department of Organic Synthesis and Process Chemistry

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad-500007

4. India

Abstract

An efficient, cost effective and protecting group tolerant CuBr₂-catalyzed synthesis of 2,6-trans-disubstituted tetrahydropyran with excellent diastereoselectivity, demonstrated in the total synthesis of decytospolides A and B and their C6-epimers.

Funder

Science and Engineering Research Board

Council of Scientific and Industrial Research, India

University Grants Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/OB/C9OB02689D

Reference98 articles.

1. Macrocyclization by Ring-Closing Metathesis in the Total Synthesis of Natural Products: Reaction Conditions and Limitations

2. Fijianolides, polyketide heterocycles from a marine sponge

3. Zampanolide, a new cytotoxic marcrolide from a marine sponge

4. Isolation and spectroscopic structure elucidation of sorangicin a, a new type of macrolide-polyether antibiotic from gliding bacteria - XXX.

5. Scytophycins, cytotoxic and antimycotic agents from the cyanophyte Scytonema pseudohofmanni

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Asymmetric Total Synthesis of Lobophopyranone A and B;Synthesis;2024-06-04

2. Brønsted acid-mediated selective α-alkenylation of 3,4-dihydro-2H-pyrans;Organic Chemistry Frontiers;2024