A ligand strand that displays anion-dependant reactivity with acetonitrile; formation of either a mononuclear complex or head-to-tail circular helicate
Author:
Affiliation:
1. Department of Chemical and Biological Sciences
2. University of Huddersfield
3. Huddersfield
4. UK
Abstract
The ligand L2,2 contains two bidentate domains separated by a 3,3-diamino-2,2′-biphenyl spacer unit and with Cu(ClO4)2 a mononuclear species is formed (e.g. [Cu(L2,2)]2+).
Funder
University of Huddersfield
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01063G
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4. “Let's Twist Again”Double-Stranded, Triple-Stranded, and Circular Helicates
5. Dicatechol ligands: novel building-blocks for metallo-supramolecular chemistry
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