Complexity in structure-directed prebiotic chemistry. Reaction bifurcation from a β-diketone in tetrapyrrole formation
Author:
Affiliation:
1. Department of Chemistry
2. North Carolina State University
3. Raleigh
4. USA
Abstract
An unsymmetrical β-diketone with δ-aminolevulinic acid affords both a “defective” and a “normal” pyrrole; upon combinatorial reaction the former terminates chain-growth of the latter on the path to tetrapyrrole macrocycles.
Funder
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C6NJ00545D
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2. Synthesis of diverse acyclic precursors to pyrroles for studies of prebiotic routes to tetrapyrrole macrocycles;New Journal of Chemistry;2016
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