An investigation on the second-order nonlinear optical response of cationic bipyridine or phenanthroline iridium(iii) complexes bearing cyclometallated 2-phenylpyridines with a triphenylamine substituent

Author:

Hierlinger Claus12345,Cordes David B.678910ORCID,Slawin Alexandra M. Z.678910ORCID,Colombo Alessia1112131415ORCID,Dragonetti Claudia1112131415ORCID,Righetto Stefania11121314,Roberto Dominique1112131415ORCID,Jacquemin Denis161718195ORCID,Zysman-Colman Eli678910ORCID,Guerchais Véronique12345ORCID

Affiliation:

1. Univ Rennes

2. CNRS

3. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226

4. F-35000 Rennes

5. France

6. Organic Semiconductor Centre

7. EaStCHEM School of Chemistry

8. University of St Andrews

9. St Andrews, Fife

10. UK

11. Dipartimento di Chimica dell'Università degli Studi di Milano

12. UdR-INSTM

13. Milano

14. Italy

15. ISTM-CNR

16. UMR CNRS 6230

17. Université de Nantes

18. CEISAM

19. 44322 Nantes Cedex 3

Abstract

A novel cationic Ir(iii) complex, characterized by a large NLO response, can be incorporated into a polymeric film leading to a good second-harmonic generation.

Funder

Ministero dell’Istruzione, dell’Università e della Ricerca

Consiglio Nazionale delle Ricerche

University of St Andrews

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference61 articles.

1. J. Zyss , J. Molecular Nonlinear Optics: Materials, Physics and Devices , Academic Press , Boston , 1994

2. N. P. Prasad and D. J.Williams , in Introduction to Nonlinear Optical Effects in molecules and Polymers , Wiley , 1991

3. Coordination and organometallic compounds and inorganic–organic hybrid crystalline materials for second-order non-linear optics

4. Switchable Nonlinear Optical Metallochromophores with Pyridinium Electron Acceptor Groups

5. Organotransition Metal Complexes for Nonlinear Optics

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