A novel Pt(iv) mono azido mono triazolato complex evolves azidyl radicals following irradiation with visible light-Reference-Cited by-同舟云学术

A novel Pt(iv) mono azido mono triazolato complex evolves azidyl radicals following irradiation with visible light

Published:2019 Issue:19 Volume:48 Page:6416-6420
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Yao Kezi¹²³⁴,Bertran Arnau¹²³⁴,Morgan Jacques¹²³⁴,Hare Samuel M.¹²³⁴,Rees Nicholas H.¹²³⁴,Kenwright Alan M.⁵⁶⁷⁴^ORCID,Edkins Katharina⁸⁹¹⁰⁴^ORCID,Bowen Alice M.¹²³⁴^ORCID,Farrer Nicola J.¹²³⁴^ORCID

Affiliation:

1. Chemistry Research Laboratory

2. University of Oxford

3. Oxford

4. UK

5. School of Pharmacy

6. Queen's University Belfast

7. Belfast BT9 7BL

8. Department of Chemistry

9. University of Durham

10. Durham DH1 3LE

Abstract

A novel Pt^IV azido triazolato complex exists as an equilibrium between two species in d₃-MeCN and evolves azide radicals (but not hydroxide radicals) when irradiated with visible light.

Funder

Wellcome Trust

Cancer Research UK

John Fell Fund, University of Oxford

Engineering and Physical Sciences Research Council

Royal Society

Keble College, University of Oxford

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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