Switching of the mechanism of charge transport induced by phase transitions in tunnel junctions with large biomolecular cages

Author:

Gupta Nipun Kumar12,Pasula Rupali Reddy3,Karuppannan Senthil Kumar1ORCID,Ziyu Zhang1,Tadich Anton4,Cowie Bruce4,Qi Dong-Chen5,Bencok Peter6,Lim Sierin37ORCID,Nijhuis Christian A.128ORCID

Affiliation:

1. Department of Chemistry, National University of Singapore, 3 Science Drive, Singapore 117543, Singapore

2. Centre for Advanced 2D Materials, National University of Singapore, 6 Science Drive 2, Singapore 117546, Singapore

3. School of Chemical and Biomedical Engineering, Nanyang Technological University, 70 Nanyang Drive, Singapore 637457, Singapore

4. Australian Synchrotron Clayton, Victoria 3168, Australia

5. Centre for Materials Science, School of Chemistry and Physics, Queensland University of Technology, Brisbane, Queensland 4001, Australia

6. I10, Diamond Light Source Ltd, Diamond House, Harwell Science & Innovation Campus, Didcot, Oxfordshire, OX11 0DE, UK

7. NTU-Northwestern Institute for Nanomedicine, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore

8. Hybrid Materials for Opto-Electronics Group, Department of Molecules and Materials, Faculty of Science and Technology, University of Twente, 7500 AE Enschede, The Netherlands

Abstract

This work gives new insights in the conduction mechanisms across biomolecular junctions and demonstrates that proteins can reversibly change between in- and coherent tunnelling pathways defined by the protein cage and the amount of co-factor.

Funder

Ministry of Education - Singapore

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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