Photochemical or electrochemical bond breaking – exploring the chemistry of (μ2-alkyne)Co2(CO)6 complexes using time-resolved infrared spectroscopy, spectro-electrochemical and density functional methods
Author:
Affiliation:
1. School of Chemical Sciences
2. Dublin City University
3. Dublin 9
4. Ireland
5. Central Laser Facility
6. Science & Technology Facilities Council
7. Research Complex at Harwell
8. Rutherford Appleton Laboratory
9. Didcot
Abstract
The photoassisted Pauson–Khand reaction involves the formation of a high-spin diradical species and not CO loss as previously thought.
Funder
Environmental Protection Agency
Sustainable Energy Authority of Ireland
Central Laser Facility, Science and Technology Facilities Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03006A
Reference69 articles.
1. Ferrocene Derivatives. Part I. The Direct Synthesis of Substituted Ferrocenes
2. Organometallic photochemistry at the end of its first century
3. Chemical Reactions Produced by Very High Light Intensities
4. Matrix Isolation Method for the Experimental Study of Unstable Species
5. Organometallic mediated radical polymerization
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