Reaction-activated palladium catalyst for dehydrogenation of substituted cyclohexanones to phenols and H2 without oxidants and hydrogen acceptors-Reference-Cited by-同舟云学术

Reaction-activated palladium catalyst for dehydrogenation of substituted cyclohexanones to phenols and H2 without oxidants and hydrogen acceptors

Published:2015 Issue:8 Volume:6 Page:4674-4680
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhang Jingwu¹²³⁴,Jiang Qiangqiang¹²³⁴,Yang Dejun¹²³⁴,Zhao Xiaomei¹²³⁴,Dong Yanli¹²³⁴,Liu Renhua¹²³⁴

Affiliation:

1. School of Pharmacy

2. East China University of Science and Technology

3. Shanghai 200237

4. China

Abstract

A combination of Pd/C and H₂ is found to dehydrogenate a wide range of substituted cyclohexanones and 2-cyclohexenones to their corresponding phenols with high isolated yields, with H₂ as the only byproduct.

Funder

National Natural Science Foundation of China

Ministry of Science and Technology of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01044F

Reference38 articles.

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4. Preparation and Photochemical Rearrangements of 2-Phenyl-2,5-cyclohexadien-1-ones. An Efficient Route to Highly Substituted Phenols

5. Dehydrative C–H Alkylation and Alkenylation of Phenols with Alcohols: Expedient Synthesis for Substituted Phenols and Benzofurans

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