Microstructures of negative and positive azeotropes

Author:

Shephard J. J.12341,Callear S. K.5674,Imberti S.5674,Evans J. S. O.1894,Salzmann C. G.1234

Affiliation:

1. Department of Chemistry

2. University College London

3. WC1H 0AJ London

4. UK

5. ISIS Facility

6. Rutherford Appleton Laboratory

7. Didcot OX11 0QX

8. Durham University

9. Durham DH1 3LE

Abstract

Azeotropes famously impose fundamental restrictions on distillation processes, yet their special thermodynamic properties make them highly desirable for a diverse range of industrial and technological applications. Using neutron diffraction, this study provides first insights into the microstructures of azeotropes.

Funder

Royal Society

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference68 articles.

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2. J. S. Rowlinson and F. L.Swinton, Liquids and Liquid Mixtures, Butterworth Scientifics, London, 3rd edn, 1982

3. Journal review. Azeotropic distillation

4. Azeotropic phase equilibrium diagrams: a survey

5. Handbook for Critical Cleaning: Cleaning agents and systems, CRC Books, Boca Raton, USA, 2nd edn, 2011

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