Influence of surface defects on activity and selectivity: a quantitative study of structure sensitivity of Pd catalysts for acetylene hydrogenation-Reference-Cited by-同舟云学术

Influence of surface defects on activity and selectivity: a quantitative study of structure sensitivity of Pd catalysts for acetylene hydrogenation

Published:2021 Issue: Volume: Page:
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Xie Wenbo¹²³⁴,Hu P.¹²³⁴^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Queen's University Belfast

3. Belfast

4. UK

Abstract

The structure sensitivity of Pd catalysed acetylene hydrogenation is quantitatively examined using a coverage-dependent microkinetic model. Pd(211) was found to be more active than Pd(111), but present a poorer selectivity toward ethylene.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00665G

Reference67 articles.

1. Metal single-atom catalysts for selective hydrogenation of unsaturated bonds

2. A Simple Method To Locate the Optimal Adsorption Energy for the Best Catalysts Directly

3. Advances in the Design of Nanostructured Catalysts for Selective Hydrogenation

4. Seven chemical separations to change the world

5. Influence of surface structures, subsurface carbon and hydrogen, and surface alloying on the activity and selectivity of acetylene hydrogenation on Pd surfaces: A density functional theory study

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