Edge-sharing BO4 tetrahedra and penta-coordinated silicon in the high-pressure modification of NaBSi3O8

Author:

Gorelova Liudmila1ORCID,Pakhomova Anna23,Aprilis Georgios4ORCID,Yin Yuqing4,Laniel Dominique4,Winkler Bjoern5,Krivovichev Sergey16,Pekov Igor7,Dubrovinskaia Natalia48,Dubrovinsky Leonid9

Affiliation:

1. Crystallography Department, Institute of Earth Science, Saint Petersburg State University, University Emb. 7/9, 199034 St. Petersburg, Russia

2. Deutsches Elektronen-Synchrotron (DESY), Petra III, Notkestraße 85, 22607 Hamburg, Germany

3. European Synchrotron Radiation Facility, 71 Av. des Martyrs, 38000 Grenoble, France

4. Material Physics and Technology at Extreme Conditions, Laboratory of Crystallography, University of Bayreuth, 95440, Bayreuth, Germany

5. Institute für Geowissenschaften, Frankfurt University, Altenhöferallee 1, DE-60438 Frankfurt am Main, Germany

6. Kola Science Centre, Russian Academy of Sciences, Fersman str. 14, 184209 Apatity, Russia

7. Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia

8. Department of Physics, Chemistry and Biology (IFM), Linkoeping University, SE-581 83, Linkoeping, Sweden

9. Bayerisches Geoinstitut, University of Bayreuth, Universitätsstraße 30, 95447 Bayreuth, Germany

Abstract

High-pressure modification of NaBSi3O8 results in the first example of a borosilicate compound containing edge-sharing BO4 tetrahedra and SiO5 polyhedra.

Funder

Deutsche Forschungsgemeinschaft

Council on grants of the President of the Russian Federation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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