2-Azabutadiene complexes of rhenium(i): S,N-chelated species with photophysical properties heavily governed by the ligand hidden traits-Reference-Cited by-同舟云学术

2-Azabutadiene complexes of rhenium(i): S,N-chelated species with photophysical properties heavily governed by the ligand hidden traits

Published:2021 Issue:8 Volume:50 Page:2945-2963
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Schlachter Adrien¹²³⁴^ORCID,Juvenal Frank¹²³⁴,Kinghat Tangou Rodolphe⁵⁶⁷⁸⁹,Khatyr Abderrahim⁵⁶⁷⁸⁹,Guyon Fabrice⁵⁶⁷⁸⁹,Karsenti Paul-Ludovic¹²³⁴,Strohmann Carsten¹⁰¹¹¹²¹³,Kubicki Marek M.¹⁴⁷¹⁵⁹,Rousselin Yoann¹⁴⁷¹⁵⁹,Harvey Pierre D.¹²³⁴^ORCID,Knorr Michael⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. Département de Chimie

2. Université de Sherbrooke

3. Sherbrooke

4. Canada J1 K 2R1

5. Institut UTINAM

6. UMR CNRS 6213

7. Université Bourgogne Franche-Comté

8. 25030 Besançon

9. France

10. Anorganische Chemie

11. Technische Universität Dortmund

12. 44227 Dortmund

13. Germany

14. Institut de Chimie Moléculaire UMR 5260

15. 21078 Dijon

Abstract

The S,N-coordination of azabutadienes onto fac-Re(CO)₃X species creates moderately emissive complexes, which exhibit ultrafast and multiphasic deactivation kinetics of both their singlet and triplet (MLCT/ILCT) excited states.

Funder

Natural Sciences and Engineering Research Council of Canada

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D0DT04183A

Reference113 articles.

1. Photophysical properties and applications of Re(I) and Re(I)–Ru(II) carbonyl polypyridyl complexes

2. Exploitation of Luminescent Organometallic Rhenium(I) and Iridium(III) Complexes in Biological Studies

3. Sensitized Photochemical CO 2 Reduction by Hetero‐Pacman Compounds Linking a Re I Tricarbonyl with a Porphyrin Unit

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