Lewis acidic FeCl3 promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate-Reference-Cited by-同舟云学术

Lewis acidic FeCl3 promoted 2-aza-Cope rearrangement to afford α-substituted homoallylamines in dimethyl carbonate

Published:2019 Issue:31 Volume:9 Page:18013-18017
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gadde Karthik¹²³⁴⁵^ORCID,Daelemans Jonas¹²³⁴⁵,Maes Bert U. W.¹²³⁴⁵^ORCID,Abbaspour Tehrani Kourosch¹²³⁴⁵^ORCID

Affiliation:

1. Organic Synthesis

2. Department of Chemistry

3. University of Antwerp

4. 2020 Antwerp

5. Belgium

Abstract

The current work shows an iron-catalyzed 2-aza-Cope rearrangement in dimethyl carbonate for the synthesis of a wide variety of α-substituted homoallylamines from readily accessible starting materials with diverse functional groups.

Funder

Universiteit Antwerpen

Fonds Wetenschappelijk Onderzoek

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/RA/C9RA03277K

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