Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility-Reference-Cited by-同舟云学术

Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility

Published:2022 Issue:8 Volume:58 Page:1139-1142
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ma Yunsheng¹²^ORCID,Tang Xiaoyan¹²^ORCID,Chen Ming¹,Mishima Akio²,Li Liangchun³^ORCID,Hori Akihiro²^ORCID,Wu Xiaoyu⁴,Ding Lifeng⁴^ORCID,Kusaka Shinpei²^ORCID,Matsuda Ryotaro²

Affiliation:

1. School of Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China

2. Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan

3. Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

4. Department of Chemistry, Xi’an JiaoTong-Liverpool University, 111 Ren’ai Road, Suzhou Dushu Lake Higher Education Town, Jiangsu Province, 215123, China

Abstract

We demonstrate the generation of a MOF (Zn8-as) based on octa-nuclear zinc clusters from a curved ligand and Zn(ii) in DMF and H2O. Zn8-de displays gated adsorption for C2H2 and type-I adsorption for CO2, attributed to the framework flexibility.

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05893B

Reference57 articles.

1. Structural and dynamic studies of substrate binding in porous metal–organic frameworks

2. Construction of Flexible‐on‐Rigid Hybrid‐Phase Metal–Organic Frameworks for Controllable Multi‐Drug Delivery

3. Solvent‐Induced Control over Breathing Behavior in Flexible Metal–Organic Frameworks for Natural‐Gas Delivery

4. Collective Breathing in an Eightfold Interpenetrated Metal–Organic Framework: From Mechanistic Understanding towards Threshold Sensing Architectures

5. Stitching 2D Polymeric Layers into Flexible Interpenetrated Metal-Organic Frameworks within Single Crystals

Cited by 9 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Octanuclear Zinc Clusters in Microporous Organic Polymers: Network‐Enhanced Reductive CO₂ Fixation to Formamides at Room Temperature;Small;2024-08-20

2. Solvent-Driven Switchable Structural Deformations in a Flexible Metal–Organic Framework with Pyrrolo-Pyrrole–Based Linker;Crystal Growth & Design;2024-06-12

3. A multi-functionalized MOF with unique molecular-sized pockets for excellent lead(II) removal and selective separation of C3H8/CH4;Separation and Purification Technology;2023-11

4. Discriminatory Gate‐Opening Effect in a Flexible Metal–Organic Framework for Inverse CO₂/C₂H₂ Separation;Small;2023-05-17

5. Effect of Linker Structure and Functionalization on Secondary Gas Formation in Metal–Organic Frameworks;The Journal of Physical Chemistry A;2023-03-22