Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility-Reference-Cited by-同舟云学术

Design of a MOF based on octa-nuclear zinc clusters realizing both thermal stability and structural flexibility

Published:2022 Issue:8 Volume:58 Page:1139-1142
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ma Yunsheng¹²^ORCID,Tang Xiaoyan¹²^ORCID,Chen Ming¹,Mishima Akio²,Li Liangchun³^ORCID,Hori Akihiro²^ORCID,Wu Xiaoyu⁴,Ding Lifeng⁴^ORCID,Kusaka Shinpei²^ORCID,Matsuda Ryotaro²

Affiliation:

1. School of Materials Engineering, Jiangsu Key Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500, China

2. Department of Materials Chemistry, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan

3. Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering, Tongji University, Shanghai 200092, China

4. Department of Chemistry, Xi’an JiaoTong-Liverpool University, 111 Ren’ai Road, Suzhou Dushu Lake Higher Education Town, Jiangsu Province, 215123, China

Abstract

We demonstrate the generation of a MOF (Zn8-as) based on octa-nuclear zinc clusters from a curved ligand and Zn(ii) in DMF and H2O. Zn8-de displays gated adsorption for C2H2 and type-I adsorption for CO2, attributed to the framework flexibility.

Funder

Core Research for Evolutional Science and Technology

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D1CC05893B

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