Significance of the electron-density of molecular fragments on the properties of manganese(iii) β-diketonato complexes: an XPS and DFT study-Reference-Cited by-同舟云学术

Significance of the electron-density of molecular fragments on the properties of manganese(iii) β-diketonato complexes: an XPS and DFT study

Published:2017 Issue:44 Volume:7 Page:27718-27728
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gostynski Roxanne¹²³⁴,Conradie Jeanet¹²³⁴^ORCID,Erasmus Elizabeth¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of the Free State

3. Bloemfontein

4. South Africa

Abstract

The group electronegativity of the R-groups of the ligand influences the XPS binding energies and the amount of charge transferred in the Mn 2p_3/2 photoelectron lines. DFT studies illustrated different Jahn–Teller elongation bond stretch isomers.

Funder

National Research Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA04921H

Reference92 articles.

1. Mononuclear Manganese(III) Complexes as Building Blocks for the Design of Trinuclear Manganese Clusters: Study of the Ligand Influence on the Magnetic Properties of the [Mn3(μ3-O)]7+ Core

2. Single-Molecule Magnets: Site-Specific Ligand Abstraction from [Mn12O12(O2CR)16(H2O)4] and the Preparation and Properties of [Mn12O12(NO3)4(O2CCH2But)12(H2O)4]

3. Mixed-Valence Tetranuclear Manganese Single-Molecule Magnets

4. Experimental Evidence of a Haldane Gap in anS=2Quasi-Linear-Chain Antiferromagnet

5. Magnetic behaviour of octaethylporphyrinatomanganese(III) tetracyanoethenide, [MnOEP][TCNE], and hexacyanobutadienide, [MnOEP][C4(CN)6]: the importance of a uniform chain for stabilizing strong effective ferromagnetic coupling

Cited by 60 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Depth resolving of Fe 2p core-level photoemission during the CO2 hydrogenation reaction by lab-based soft and hard X-ray photoelectron spectroscopy;Applied Surface Science;2024-11

2. Methotrexate-loaded manganese nitrogen dual-doped carbon quantum dots as targeted nano drug-delivery system for potential use in cancer theranostics;Journal of Photochemistry and Photobiology A: Chemistry;2024-10

3. Unraveling the Fluoride-Induced Interface Reconstruction Across Lead-Based Hierarchical MnO₂ Anode in Zinc Electrowinning;Environmental Science & Technology;2024-09-04

4. Pivotal Role of Modifiable A‐Site Doping in Enhancing Valence Stability and Excited State Dynamics of MnO₆;Small Methods;2024-08-30

5. Two polymorph modifications of tris(hexafluoroacetylacetonato)iron(III) revealed: is that common for other trivalent metals?;Acta Crystallographica Section C Structural Chemistry;2024-08-14