Diferrocenylmercury diphosphine diastereomers with unique geometries: trans-chelation at Pd(ii) with short Hg(ii)⋯Pd(ii) contacts-Reference-Cited by-同舟云学术

Diferrocenylmercury diphosphine diastereomers with unique geometries: trans-chelation at Pd(ii) with short Hg(ii)⋯Pd(ii) contacts

Published:2019 Issue:35 Volume:48 Page:13430-13439
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Tagne Kuate Alain C.¹²³⁴¹^ORCID,Lalancette Roger A.¹²³⁴,Bannenberg Thomas⁵⁶⁷⁸,Tamm Matthias⁵⁶⁷⁸^ORCID,Jäkle Frieder¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Rutgers University-Newark

3. Newark

4. USA

5. Institut für Anorganische und Analytische Chemie

6. Technische Universität Braunschweig

7. 38106 Braunschweig

8. Germany

Abstract

Two isomeric diphosphine chelate ligands with divergent orientation of the ferrocenes were prepared independently and their complexation to Pd(ii) investigated.

Funder

Deutsche Forschungsgemeinschaft

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02728A

Reference68 articles.

1. J. A. Gillespsie , E.Zuidema , P. W. N. M.Leuwen and P. C. J.Kamer , Phosphorus Ligand Effects in Homogenous Catalysis and Rational Catalyst Design , in Phosphorus(III) Ligands in Homogeneous Catalysis: Design and Synthesis , ed. P. C. J. Kamer and P. W. N. M. Leuwen , Wiley , 1st edn, 2012

2. The bite angle makes the difference: a practical ligand parameter for diphosphine ligands

3. Ligand Bite Angle Effects in Metal-catalyzed C−C Bond Formation

4. Wide Bite Angle Diphosphines: Xantphos Ligands in Transition Metal Complexes and Catalysis

5. The Steric Nature of the Bite Angle

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1. Palladium(0) complexes of diferrocenylmercury diphosphines: synthesis, X-ray structure analyses, catalytic isomerization, and C–Cl bond activation;Dalton Transactions;2021

2. Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d10⋯d10, d10⋯d8, d8⋯d8) metal ions [M⋯M′ M = Hg(ii) and Pd(ii) and M′ = Cu(i), Ag(i), Au(i), and Pd(ii)];Dalton Transactions;2020