A pore-expanded supramolecular organic framework and its enrichment of photosensitizers and catalysts for visible-light-induced hydrogen production

Author:

Yan Meng12345,Liu Xu-Bo12345,Gao Zhong-Zheng12345,Wu Yi-Peng12345,Hou Jun-Li12345ORCID,Wang Hui12345,Zhang Dan-Wei12345ORCID,Liu Yi6789ORCID,Li Zhan-Ting12345ORCID

Affiliation:

1. Department of Chemistry

2. Collaborative Innovation Centre of Chemistry for Energy Materials (iChEM)

3. and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials

4. Fudan University

5. Shanghai 200438

6. The Molecular Foundry

7. Lawrence Berkeley National Laboratory

8. Berkeley

9. USA.

Abstract

A 3.6 nm-pore SOF is constructed, which adsorbs both photosensitizers and polyoxometallates for visible light-induced proton reduction to produce H2.

Funder

National Natural Science Foundation of China

U.S. Department of Energy

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Reference77 articles.

1. Porous Materials: Processing and Applications , ed. P. Liu and G. F. Chen , Butterworth-Heinemann Publisher , Oxford , 2014

2. Metal-Organic Framework Materials , ed. L. R. MacGillivray and C. M. Lukehart , John Wiley & Sons , Chichester , 2015

3. Porous Organic Frameworks: Design, Synthesis and Their Advanced Applications , ed. G. Zhu and H. Ren , Springer-Verlag , Berlin , 2015

4. A series of isoreticular chiral metal–organic frameworks as a tunable platform for asymmetric catalysis

5. Chiral covalent organic frameworks for asymmetric catalysis and chiral separation

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