Experimental and computational approaches to study the chlorination mechanism of pentlandite with ammonium chloride

Author:

Xiong Xiaolu1ORCID,Li Guangshi1,Pang Zhongya1,Chen Sha1ORCID,Zou Xingli1,Xu Qian1,Cheng Hongwei1ORCID,Li Shenggang2ORCID,Zhu Kai1,Lu Xionggang13

Affiliation:

1. State Key Laboratory of Advanced Special Steel, Shanghai Key Laboratory of Advances Ferrometallurgy, School of Materials Science and Engineering, Shanghai University, 99 Shangda Road, Shanghai 200444, China

2. CAS Key Laboratory of Low-Carbon Conversion Science and Engineering, Shanghai Advanced Research Institute, Chinese Academy of Sciences, 100 Haike Road, Shanghai 201210, China

3. School of Materials Science, Shanghai Dianji University, 300 Shuihua Road, Shanghai 200240, China

Abstract

The chlorination mechanism of pentlandite with NH4Cl has been proposed. The chlorination of pentlandite can be achieved by two pathways, where O2 plays a crucial role in promoting the chlorination process.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

China Postdoctoral Science Foundation

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

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