Probing the unpaired Fe spins across the spin crossover of a coordination polymer

Author:

Ekanayaka Thilini K.1234ORCID,Kurz Hannah5678ORCID,Dale Ashley S.910114ORCID,Hao Guanhua123412ORCID,Mosey Aaron910114ORCID,Mishra Esha1234ORCID,N’Diaye Alpha T.1213144ORCID,Cheng Ruihua910114ORCID,Weber Birgit5678ORCID,Dowben Peter A.1234ORCID

Affiliation:

1. Department of Physics and Astronomy

2. University of Nebraska

3. Lincoln

4. USA

5. Inorganic Chemistry IV

6. University of Bayreuth

7. 95447 Bayreuth

8. Germany

9. Department of Physics

10. Indiana University Purdue University-Indianapolis

11. Indianapolis

12. Advanced Light Source

13. Lawrence Berkeley National Laboratory

14. Berkeley

Abstract

For the spin crossover coordination polymer [Fe(L1)(bipy)]n (where L1 is a N2O22− coordinating Schiff base-like ligand bearing a phenazine fluorophore and bipy = 4,4′-bipyridine), there is compelling additional evidence of a spin state transition.

Funder

Division of Materials Research

Lawrence Berkeley National Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Microbiology

Reference80 articles.

1. Structural approach of the features of the spin crossover transition in iron (II) compounds

2. Molecular spin crossover phenomenon: recent achievements and prospects

3. Spin crossover phenomena in Fe(ii) complexes

4. Structure:function relationships in molecular spin-crossover complexes

5. P. Gütlich and H. A.Goodwin , in Spin Crossover in Transition Metal Compounds I , ed. P. Gütlich and H. A. Goodwin , Topics in Current Chemistry, Springer , Berlin, Heidelberg , 2004 , vol. 233, pp. 253–255

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