Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung-Reference-Cited by-同舟云学术

Turning unreactive copper acetylides into remarkably powerful and mild alkyne transfer reagents by oxidative umpolung

Published:2014 Issue:70 Volume:50 Page:10008-10018
ISSN:1359-7345
Container-title:Chem. Commun.
language:en
Short-container-title:Chem. Commun.

Author:

Evano G.¹²³⁴,Jouvin K.⁵⁶⁷⁸,Theunissen C.¹²³⁴,Guissart C.¹²³⁴,Laouiti A.⁵⁶⁷⁸⁹,Tresse C.¹⁰¹¹¹²,Heimburger J.⁵⁶⁷⁸,Bouhoute Y.¹²³⁴,Veillard R.¹³¹⁴¹⁵¹⁶¹⁷,Lecomte M.¹²³⁴,Nitelet A.¹²³⁴,Schweizer S.¹⁰¹¹¹²,Blanchard N.¹⁸¹⁹²⁰²¹,Alayrac C.¹³¹⁴¹⁵¹⁶¹⁷,Gaumont A.-C.¹³¹⁴¹⁵¹⁶¹⁷

Affiliation:

1. Laboratoire de Chimie Organique

2. Service de Chimie et PhysicoChimie Organiques

3. Université Libre de Bruxelles

4. 1050 Brussels, Belgium

5. Institut Lavoisier de Versailles

6. UMR CNRS 8180

7. Université de Versailles Saint-Quentin-en-Yvelines

8. 78035 Versailles Cedex, France

9. Laboratoire de Chimie Hétérocyclique

10. Laboratoire de Chimie Organique et Bioorganique

11. Université de Haute-Alsace-ENSCMu

12. 68093 Mulhouse cedex, France

13. Laboratoire de Chimie Moléculaire et Thioorganique

14. UMR CNRS 6507

15. INC3M

16. FR3038

17. ENSICAEN & Université de Caen Basse-Normandie

18. Laboratoire de Chimie Moléculaire

19. ECPM-CNRS UMR7509

20. Université de Strasbourg

21. 67087 Strasbourg, France

Abstract

Upon oxidation, copper acetylides formally behave as highly electrophilic species that could be trapped by a wide range of nucleophiles.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CC/C4CC03198A

Reference102 articles.

1. Ynamides: Versatile Tools in Organic Synthesis

2. Ynamides: A Modern Functional Group for the New Millennium

3. Highly Regio- and Stereoselective Nickel-Catalyzed Addition of Dialkyl Phosphites to Ynamides: an Efficient Synthesis of β-Aminovinylphosphonates

4. De Novo Synthesis of 1,4-Dihydropyridines and Pyridines

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