Vibrational predissociation versus intramolecular vibrational energy redistribution (IVR) in rare gas⋯dihalogen complexes: IVR identified in Ar⋯I2(B, ν′) using velocity-map imaging-Reference-Cited by-同舟云学术

Vibrational predissociation versus intramolecular vibrational energy redistribution (IVR) in rare gas⋯dihalogen complexes: IVR identified in Ar⋯I2(B, ν′) using velocity-map imaging

Published:2021 Issue:46 Volume:23 Page:26108-26119
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Makarem Camille¹,Wei Jie¹,Loomis Richard A.¹^ORCID,Darr Joshua P.²^ORCID

Affiliation:

1. Department of Chemistry, Washington University in St. Louis, One Brookings Drive, CB 1134, Saint Louis, MO 63130, USA

2. Department of Chemistry, University of Nebraska at Omaha, 6001 Dodge St, DSC 337, Omaha, NE 68182, USA

Abstract

Contributions from competing relaxation pathways can be difficult to identify, but direct evidence for IVR in the dissociation of excited-state Ar···I2(B, v') complexes was obtained using ion product velocity map imaging.

Funder

American Chemical Society Petroleum Research Fund

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP04727B

Reference66 articles.

1. The photodissociation of van der Waals molecules: Complexes of iodine, neon, and helium

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