The ability of the NiSOD binding loop to chelate zinc(ii): the role of the terminal amino group in the enzymatic functions

Author:

Csire Gizella1234ORCID,Kolozsi András1564,Gajda Tamás1564ORCID,Pappalardo Giuseppe789ORCID,Várnagy Katalin1234ORCID,Sóvágó Imre1234ORCID,Fábián István123410ORCID,Lihi Norbert123410ORCID

Affiliation:

1. Department of Inorganic and Analytical Chemistry

2. University of Debrecen

3. Debrecen

4. Hungary

5. University of Szeged

6. Szeged

7. CNR-IBB Istituto di Biostrutture e Bioimmagini

8. 95126 Catania

9. Italy

10. MTA-DE Redox and Homogeneous Catalytic Reaction Mechanisms Research Group

Abstract

Equilibrium and spectroscopic characterization of zinc(ii) complexes with NiSOD related peptides highlights the crucial role of terminal amino groups in the enzymatic function.

Funder

European Regional Development Fund

Magyar Tudományos Akadémia

Consiglio Nazionale delle Ricerche

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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