Rationale for the reactivity differences between main group and d0 transition metal complexes toward olefin polymerisation
Author:
Affiliation:
1. Department of Chemistry
2. Alzahra University
3. Tehran
4. Iran
5. Islamic Azad University
6. Central Tehran Branch
7. School of Natural Science (Chemistry)
8. University of Tasmania
9. Hobart
10. Australia
Abstract
A ring strain in a four-membered ring transition structure plays an important role in controlling the activation barrier to an olefin insertion into a M–R bond.
Funder
Alzahra University
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01017C
Reference77 articles.
1. Precise Control of Polyolefin Stereochemistry Using Single-Site Metal Catalysts
2. Cocatalysts for Metal-Catalyzed Olefin Polymerization: Activators, Activation Processes, and Structure−Activity Relationships
3. Modeling Metal-Catalyzed Olefin Polymerization
4. Selectivity in Propene Polymerization with Metallocene Catalysts
5. Recent developments in olefin polymerizations with transition metal catalysts
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