pH-Dependent solution dynamics of a manganese(ii) polyoxometalate, [Mn4(H2O)2(P2W15O56)2]16−, and [Mn(H2O)6]2+-Reference-Cited by-同舟云学术

pH-Dependent solution dynamics of a manganese(ii) polyoxometalate, [Mn4(H2O)2(P2W15O56)2]16−, and [Mn(H2O)6]2+

Published:2015 Issue:44 Volume:44 Page:19068-19071
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sharma Rupali¹²³,Zhang Jie¹²³,André Ohlin C.¹²³

Affiliation:

1. School of Chemistry

2. Monash University

3. Australia

Abstract

The NMR-determined pH-dependent water–ligand exchange rate of a Mn(ii)-polyoxometalate varies by more than an order of magnitude, in contrast with those of a hexa-aqua ion.

Funder

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT03138A

Reference18 articles.

1. NMR‐Relaxation Mechanisms of O17in Aqueous Solutions of Paramagnetic Cations and the Lifetime of Water Molecules in the First Coordination Sphere

2. Erratum: NMR‐Relaxation Mechanisms of 17O in Aqueous Solutions of Paramagnetic Cations and the Lifetime of Water Molecules in the First Coordination Sphere

3. Water exchange between solvent and aquomanganese(II) and aquophenanthrolinemanganese(II) complexes

4. High-pressure oxygen-17 NMR evidence for a gradual mechanistic changeover from Ia to Id for water exchange on divalent octahedral metal ions going from manganese(II) to nickel(II)

5. Mechanistic information from volume profiles for water exchange and complex-formation reactions of aquated Ni(II). pH, buffer and medium effects

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Solution NMR of transition metal complexes;Comprehensive Inorganic Chemistry III;2023

2. Diagnostic value of miR-637 in patients with atherosclerosis and its predictive significance for the future cardiovascular events;Vascular;2020-12-06

3. Direct Single- and Double-Side Triol-Functionalization of the Mixed Type Anderson Polyoxotungstate [Cr(OH)3W6O21]6–;Inorganic Chemistry;2018-12-13

4. Three Different Modes of Association between Metal Cations in Heterometallic Uranyl–Co III and Uranyl–Mn II Species;European Journal of Inorganic Chemistry;2018-10-18

5. 17 O NMR as a Tool in Discrete Metal Oxide Cluster Chemistry;Annual Reports on NMR Spectroscopy;2018